Insulation - thoughts on the first condensing surface concept
Water vapor will condense as soon as it encounters a surface with temperature below the dew point. The best strategy is to prevent that from happening by making sure any surface air can get to never reaches dew point. Insulation moves the dew point from the metal van skin to somewhere in the middle of the insulation thickness. But with batt insulation, water vapor tends not to condense on fine fibers, but continues to move through until it reaches the cold inside surface of the van skin, where it will condense. With fully adhered closed cell foam and spray foam, air cannot reach the cold metal, and the inside surface of the foam is above dew point - no condensation. When insulating with batts or pieces of rigid foam, meticulous sealing is necessary to minimize air movement into the space between van body and interior finish. A small hole or open seam allow LOTS of air and its moisture to enter the concealed space. Far more than vapor diffusion. Polyethylene and reflectex vapor barriers are not the answer. First, they're far too easily punctured and torn. Penetrations for wires, anchors, electrical boxes are hard to seal. Second, since moisture WILL get into the concealed space, there must be a way for it to dry off later, ideally by sun shining on the exterior heating up the concealed space and driving water vapor through a vapor permiable interior finish. Otherwise, trapped moisture = inevitable corrosion, unless you never camp or cook in cool climates.
Spray foam is totally adhered, but has its own special problems. Tendency to get between ribs and exterior skin, then expanding to cause ripples. Tendency to plug weep holes. Hard to go back and run new wiring. Tricky to mix perfectly for 100% reaction with no residual outgassing (urethane is a potent sensitizer). So it seems the best solution is fully adhered flexible closed cell foam wherever possible. Polyethylene from foambymail or Kflex / Armorflex duct soundproofing insulation. Contact cement - use a proper respirator! Hard to reach rib cavities could be stuffed with batt insulation then wrapped with vapor permiable house wrap (Tyvek) with all edges sealed. Generally not worth the trouble - the thermal conductivity of the rib dwarfs heat loss through the air space inside it. Finish with plywood. I'm not so sure polycarbonate or FRP or load protection polypropylene panels are such a good choice due to zero vapor permiability. Thought about Homosote as an option, but suspect it can't hold up to road vibration. Maybe marine hull liner, but I'd want to know its vapor permiability first. Then there's the question of outgassing from the contact cement...I think this drops off quickly because the quantity and thickness is minimal once the solvent evaporates. It might be worthwhile to investigate carpet and flooring adhesives with "green" indoor air quality (IAQ) ratings. They're water-based, but I can tell you from experience, they are VERY sticky...and get all over everything just as easily as contact cement.