I understand that starter battery with CCP1 powers all 12v electrical so perhaps that's why it's paired with 60a fuse.
Not true. Both batteries identical and are wired in parallel, and both batteries support all loads. I believe that may be different in Europe, but this is the USA forum... More discussion on CCP1 below.
with both alternators being HD 250amp, why is CCP1 is 60a fused and CCP2 is 175a fused?
would it be ok to swap out the 60a for a 174a ahead of CCP1?
CCP1 and CCP2 are quite different.
CCP1 is "always on", even if the key is off. The value of CCP1 is that you can use it anytime. It does have a 'battery guard' protection, Ford will turn it off when the battery gets low, but generally - it's always on. That's pretty neat. It would not make sense to pull more than 60amps with the engine off.
CCP2 is tied to the engine-run. 175a is available when the Engine is running, and shuts off a short time after engine shut-down. (actually up to 30 minutes later).
Given the differences, they aren't interchangeable. You can't just swap one for the other. Both are built into a module underneath the driver-seat, and the circuits are very different. It would be major-surgery to change them both to 175 amps.
It's also the case that while each Alternator is 250amps, the overall capacity remains 250 amps, and that needs to support the operation of the vehicle, which can be estimated at 50-70 amps. That means even with Dual Alternators, there's at most somewhere around 190 amps available after powering the Ford system. Pull any more than that and you're eating into the batteries. Busbars and wire-sizes under the seat are not sized for 350+amp loads.
From the testing that some forum members here did, the value of dual-alternators is that the system is much less likely to have load-shedding events while idling.
Here's the Ford RPM to Alternator power chart: At Idle a single alternator only has about 80amps available, and that also needs to power the van system itself. Dual alternators doubles the low-RPM available amps. (note, those are Alternator RPMs which are 2.7X engine RPM). Typical idle RPM in yellow.
That said, I have a fairly big battery (8kwh), and I can pull 120amps from CCP2... I'm pretty happy with that. There are easy ways I can pull more :
Easy :add 50 amps to CCP1
Medium: wire directly to battery, implement load-shedding
Hard: Add aftermarket alternator
But... I just don't think that juice is worth the squeeze. Maybe my opinion there will change when I get my second 8khw battery installed.